海水侵蚀环境下固化淤泥土氯离子扩散规律及微观机理研究

    STUDY ON THE LAW AND MICROSCOPIC MECHANISM OF CHLORIDE ION DIFFUSION IN SOLIDIFIED SILT SOIL UNDER SEAWATER EROSION ENVIRONMENT

    • 摘要: 为研究在海水侵蚀环境下对海洋工程中淤泥质黏土固化改良问题,在室内开展实验研究,分别采用不同的固化剂固化海相淤泥土,对不同配比的固化土:水泥固化土(CS)、钢渣粉水泥固化土(SSP-CS)、掺激发剂钢渣粉水泥固化土(A-SSP-CS)和矿渣粉水泥固化土(SP-CS)展开研究,分析其物理力学特性、侵蚀离子在固化土体中的扩散分布规律及侵蚀后的微观结构变化。研究结果表明:海水侵蚀下不同固化剂固化后的试样,随着侵蚀时间的增加,其质量变化率波动幅度较大,均呈现出先降低后增大的走势;侵蚀90 d后各类型固化土强度达到最大值,且SP-CS固化土试样的强度从初期就始终远高于其他固化试样;SSP-CS与A-SSP-CS固化土试样对比分析,因激发剂NaOH过多,A-SSP-CS固化土试样内部的密实性被降低,导致其强度出现下降的趋势;氯离子的运移扩散规律展现出,其含量随着深度和侵蚀龄期在不断增长,曲线变化波动大,后期平稳上升,试样中氯离子浓度的对比是:SP-CS>CS>SSP-CS>A-SSP-CS;SP-CS与SSP-CS固化土试样,在海水侵蚀后出现C-S-H胶凝体和AFT针状物等水化产物,内部孔隙较小,排列较紧密。研究结果展现出钢渣粉可替代水泥进行固化淤泥土的可行性,可为实际工程中固化土的抗侵蚀性能研究提供理论依据。

       

      Abstract: To study the solidification and improvement of silty clay in marine engineering under the environment of seawater erosion,different curing agents were used to solidify marine silt soil for indoor curing tests. For solidified soil of different proportions: cement-solidified soil(CS),steel slag powder-cement-solidified soil(SSP-CS),activator-steel slag powder-cement-solidified soil(A-SSP-CS),and slag powder-cement-solidified soil(SP-CS)were studied to analyze their physical and mechanical properties,the diffusion and distribution of erosion ions in solidified soil,and the changes of microstructure after erosion. The results show that the mass change rate of the samples cured by different curing agents fluctuates greatly with the increase of erosion time,and all of them show a trend of decreasing first and then increasing. After 90 days of erosion,the strength of each type of solidified soil reached the maximum value,and the strength of the SP-CS solidified soil sample was always much higher than that of other solidified soil samples from the initial stage. The comparison between SSP-CS and A-SSP-CS solidified soil samples shows that the internal compactness of A-SSP-CS solidified soil samples is reduced due to excessive activator NaOH,which results in a trend of decreasing strength. The transport and diffusion law of chloride ions shows that their content keeps increasing with the depth and age of erosion,the curve fluctuates greatly and steadily rises in the later period. The contrast of chloride ion concentration in the sample is :SP-CS>CS>SSP-CS>A-SSP-CS; In the SP-CS and SSP-CS solidified soil samples,hydration products such as C-S-H gelling and ATT acicular substances appear after seawater erosion,and the internal pores are small and closely arranged. The research results show that slag powder can replace cement to solidify silt soil feasibility,and can provide a theoretical basis for the study of the erosion resistance of solidified soil in practical engineering.

       

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